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𒁃 Hóa 10, giải hóa 10 chân trời sáng tạo

Lý thuyết bài 18: Hydrogen halide và một số phản ứng của ion Halide

xu hướng biến đổi nhiệt độ sôi hydrogen halide, biến đổi tính acid, ứng dụng, nhận biết ion halide

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Lý thuyết: Hydrogen halide và phản ứng của ion halide

I. Tính chất vật lí của hydrogen halide

ဣ- Ở điều kiện thường, HX tồn tại ở thể khí, tan tốt trong nước, tạo thành dung dịch hydrohalic acid tương ứng

𒆙- HF có nhiệt độ sôi cao bất thường là do HF có khả năng tạo liên kết hydrogen

- Từ HCl đến HI, nhiệt độ sôi tăng do:

🐠 + Lực tương tác van der Waals giữa các phân tử tăng

+ Khối lượng phân tử tăng

II. Hydrohalic acid

Tính acid của các hydrohalic acid

♌- Hydrogen halide tan trong nước tạo thành hydrohalic acid

- HF là acid yếu nhưng có tính ăn mòn thủy tinh

SiO2 + 4HF → SiF4↑ + 2H2O

🅺- HCl, HBr, HI là những acid mạnh, có đầy đủ tính chất hóa học chung của acid

+ Quỳ tím chuyển sang đỏ

🅘 + Tác dụng với kim loại đứng trước H trong dãy hoạt động hóa học

+ Tác dụng với basic oxide

+ Base

+ 1 số muối

III. Tính khử của các ion halide

- Các ion halide có số oxi hóa thấp nhất là -1

🐷=> Ion halide chỉ thể hiện tính khử trong phản ứng oxi hóa - khử

Ví dụ:

2KMnO₄ + 16HCl → 2KCl + 2MnCl₂ + 5Cl₂ + 8H₂O

IV. Nhận biết ion Halide trong dug dịch:

V. Ứng dụng

a) HF - Sản xuất teflon (chất chống dính ở nồi, chảo) theo sơ đồ:

- Ăn mòn thủy tinh vô cơ

SiO₂ + 4HF → SiF₄ + 2H₂O

- Trong công nghiệp, hỗn hợp có thành phần KF.3HF được dùng để điện phân nóng chảy, sản xuất F₂

b) HCl - Loại bỏ gỉ sắt trên sắt thép trước khi chuyển sang công đoạn sản xuất tiếp theo - Sản xuất hợp chất vô cơ và hữu cơ: PVC, PAC…

- Tái sinh các nhựa trao đổi ion nhừm thay thế các ion Na⁺ và Ca²⁺ = ion H⁺

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Lý thuyết bài 18: Hydrogen halide và một số phản ứng của ion Halide

Ph/hs Tham Gia Nhóm Để Cập Nhật Điểm Thi, Điểm Chuẩn Miễn Phí

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