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Cách làm bài tập điều chế ester - Hoá 12

1. Ester là gì?

Khi thay nhóm – OH ở nhóm carboxyl của carboxylic acid (RCOOH) bằng nhóm OR’ của alcohol thì được ester. Xét phản ứng sau:

2. Điều chế ester

Ester thường được điều chế bằng phản ứng ester hoá giữa carboxylic acid và alcohol với xúc tác là acid (thường dùng H2SO4 đặc).

→ Vai trò H2SO4🦋đặc = xúc tác + hút nước (giúp phản ứng theo chiều thuận, tăng hiệu suất phản ứng).

→ Có thể sử dụng phương pháp chưng cất để tách ester ra khỏi hỗn hợp, do nhiệt độ sôi của ester thấp hơn acid và alcohol.

3. Cách làm bài tập điều chế ester

Tính hiệu suất phản ứng ester hoá:

Ví dụ: Đun 12 gam acid acetic với một lượng dư ethyl alcohol (có H2SO4ꦏ đặc xúc tác). Đến khi phản ứng kết thúc thu được 11 gam  ester. Tính hiệu suất phản ứng  ester hoá?

Phương pháp

Tính số mol acetic acid; ester. Áp dụng công thức tính hiệu suất.

Lời giải

n CH3COOH = 12 : 60 = 0,2 mol

n CH3COOC2H5 = 11 : 88 = 0,125 mol

H% = \(\frac{{0,125}}{{0,2}}.100\%  = 62,5\% \)

4. Bài tập vận dụng

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